Lithium Battery Knowledge

Ternary lithium batteries generally refer to ternary polymer lithium batteries. Ternary polymer lithium battery refers to a lithium battery whose positive electrode material uses nickel cobalt lithium manganate (Li(NiCoMn)O2) ternary positive electrode material. The precursor product of ternary composite positive electrode material is nickel salt, cobalt salt, manganese salt. As the raw material, the ratio of nickel, cobalt and manganese in it can be adjusted according to actual needs. The battery with ternary material as the positive electrode is safer than the lithium cobalt oxide battery, but the voltage is too low, so it is used in mobile phones (the cut-off voltage of mobile phones is generally around 3.4V). ) will have a clear feeling of insufficient capacity.

Research published in the latest issue of the American Chemical Society "NanoLetters" shows that Chinese scientists are expected to develop a lithium battery that is resistant to combustion and explosions. This lithium battery made of new materials is flexible, low-cost and safer.

Lithium manganese iron phosphate (LMFP) is a new type of cathode material obtained by adding manganese element on the basis of LiFePO4. On the one hand, it can improve the voltage of the material system and make up for the lack of low energy density caused by low voltage of LiFePO4; The surface is coated with a carbon material conductive agent to improve the conductivity. So, what are the advantages of LMFP cathode material?

Ternary lithium-ion batteries refer to lithium-ion batteries that use three transition metal oxides of nickel, cobalt, and manganese as cathode materials. Compared with lithium iron phosphate batteries, ternary lithium-ion batteries have more average overall performance and higher energy density. high, the volume specific energy is also higher. Because it combines the advantages of lithium cobaltate, lithium nickelate and lithium manganate, its performance is better than any of the above single-component cathode materials.

Lithium manganese iron phosphate (LiMnxFe1-xPO4) is a new type of phosphate lithium-ion battery cathode material formed by doping a certain proportion of manganese (Mn) on the basis of lithium iron phosphate (LiFePO4). Through the doping of manganese element, on the one hand, the advantageous characteristics of iron and manganese can be effectively combined, and on the other hand, manganese and iron are both located in the fourth periodic subgroup and adjacent to the periodic table, and have similar ions Radius and some chemical properties, so doping will not significantly affect the original structure.

LiFePO4 battery is one of the Lithium battery, Because the cathode materials of LiFePO4 batteries are mainly compounds of phosphorus, acid, iron and lithium. Generally speaking, the voltage range of LiFePO4 battery is basically between 3.2V-3.6V. Among them, the nominal voltage is 3.2V, and the high-level termination charging voltage is 3.6V. However, the positive and negative materials, electrolytes, and production processes used by various manufacturers are different, so there will be differences in performance.

Many people will be entangled in the type of battery when purchasing new energy vehicles. In fact, the difference between ternary lithium battery and lithium iron phosphate battery mainly lies in the positive electrode material. Among them, the positive electrode material of ternary lithium battery is nickel salt, cobalt salt, manganese salt, and the positive electrode material of lithium iron phosphate battery is lithium iron phosphate. In addition, the electrolyte and anode materials of both use lithium hexafluorophosphate and graphite.

Lithium manganate battery refers to a battery whose positive electrode uses lithium manganate material. The nominal voltage of lithium manganate battery is 2.5~4.2v. Lithium manganate battery is widely used because of its low cost and good safety. Lithium manganate battery is a cathode material with low cost, good safety and low temperature performance, but the material itself is not very stable, and it is easy to decompose to generate gas, so it is mostly used in combination with other materials to reduce the cost of the cell, but its cycle The lifespan decays rapidly, bulging easily occurs, the high temperature performance is poor, and the lifespan is relatively short. It is mainly used for large and medium-sized batteries. In terms of power batteries, its nominal voltage is 3.7V.

With the development of lithium battery technology, there are more and more types of cylindrical lithium batteries. Cylindrical lithium ion batteries are divided into lithium cobalt oxide, lithium manganate, and ternary materials. The three material system batteries have different advantages. Let's take a look at the models and specifications of cylindrical lithium batteries.

A slight swelling of the polymer lithium battery will affect the use, reduce the battery performance, and in severe cases will burst the packaging aluminum foil, causing leakage and corrosion. Next, let's analyze the reasons for the inflation of polymer lithium batteries.